Synthesis, crystallographic, spectroscopic studies and biological activity of new cobalt(II) complexes with bioactive mixed sulindac and nitrogen-donor ligands
نویسندگان
چکیده
منابع مشابه
Synthesis, crystallographic, spectroscopic studies and biological activity of new cobalt(II) complexes with bioactive mixed sulindac and nitrogen-donor ligands
Four novel complexes [Co(H2O)4(sul)2] 1, [Co(2-ampy)2(sul)2] 2, [Co(H2O)2(1,10-phen) (sul)2] 3 and [Co(2,9-dimephen)(sul)2] 4 (sul = sulindac, 2-ampy = 2-amino pyridine, 1,10-phen = 1,10-phenanthroline and 2,9-dimeph = 2,9-dimethyl-1,10-phenanthroline) were prepared and characterized by IR, UV-Visible spectroscopy and magnetic properties. The crystal structures of complexes 1 and 4 were determi...
متن کاملsynthesis and dna interaction studies of new cobalt (ii) complexes containing different dinitrogen aaromatic ligands with calf thymus dna using different spectroscopy methods
در این مطالعه بر هم کنش این چهار کمپلکس با dna تیموس گوساله توسط روش های اسپکتروفتومتری، فلوریمتری، دو رنگ نمائی دورانی، و ویسکوزیمتری بررسی شدند تا اثر استخلاف های متیل بر روی لیگاندهای فنانترولین بررسی گردد.
Synthesis and characterization of some transition metal complexes with new mixed-donor schiff base ligands derived from 2-hydroxynaphthaldehyde
2-[3-(2-Formylnaphthoxy)-2-hydroxypropoxy] naphthaldehyde (1) have been prepared by reaction of 2-hydroxynaphthaldehyde with 1,3-dichloro-2-propanol. New N2O3 macro-acyclic ligands (L1, L2) synthesized from the reaction of (1) with aniline or cyclohexylamine. Ni (II), Co (II) and Cu (II) complexes was prepared from reaction of Schiff-bases with metal chloride and nitrate salts. All of these com...
متن کاملSynthesis and characterization of some transition metal complexes with new mixed-donor schiff base ligands derived from 2-hydroxynaphthaldehyde
2-[3-(2-Formylnaphthoxy)-2-hydroxypropoxy] naphthaldehyde (1) have been prepared by reaction of 2-hydroxynaphthaldehyde with 1,3-dichloro-2-propanol. New N2O3 macro-acyclic ligands (L1, L2) synthesized from the reaction of (1) with aniline or cyclohexylamine. Ni (II), Co (II) and Cu (II) complexes was prepared from reaction of Schiff-bases with metal chloride and nitrate salts. All of these com...
متن کاملsynthesis and characterization of potentially biological active cyclometallated organoplatinum(ii) complexes
this work is presented in five parts. in the first part preparation of the starting complex [pt(c^n)cl(dmso)], 1, in which c^n = n(1),c(2?)-chelated, deprotonated 2-phenylpyridine, and dmso = dimethylsulfoxide, and its reaction with 1 equiv of the biphosphine ligands bis(diphenylphosphino)amine, dppa, or bis(diphenylphosphino)methane, dppm, to give the complex [pt(c^n)cl(dppa)], 2, or [pt(c^n)c...
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ژورنال
عنوان ژورنال: Chemistry Central Journal
سال: 2017
ISSN: 1752-153X
DOI: 10.1186/s13065-017-0268-2